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Will Silicon batteries be a major game changer?

Arthur Hanson

Well-known member
It's new and all the information is not out, but it looks like the battery world may have a major game changer. Any thoughts or additions sought and welcome. Could these batteries be the ultimate game changer?

 
Looks good. There have been multiple attempts to solve the Si anode construction - the capacity potential is well known but controlling the swelling that occurs when Li binds to the silicon has been a tough problem. A few specialist high performance/high cost cells are in the market with some form of porous silicon anode. If this really works but without the high costs it could make a big difference. The proof will be in the scaling up.
 
From Battery University, quite a few possible benefits : https://batteryuniversity.com/article/bu-212-future-batteries

Sodium-ion (Na-ion)
Sodium-ion represents a possible lower-cost alternative to Li-ion as sodium is inexpensive and readily available. Put aside in the late 1980s in favor of lithium, Na-ion has the advantage that it can be completely discharged without encountering stresses that are common with other battery systems. The battery can also be shipped without having to adhere to Dangerous Goods Regulations. Some cells have 3.6V, and the specific energy is about 90Wh/kg with a cost per kWh that is similar to the lead acid battery. Further development will be needed to improve the cycle count and solve the large volumetric expansion when the battery is fully charged.
 
Sodium-ion (Na-ion)
Some cells have 3.6V, and the specific energy is about 90Wh/kg with a cost per kWh that is similar to the lead acid battery. Further development will be needed to improve the cycle count and solve the large volumetric expansion when the battery is fully charged.
Being tried now in some low-range cheap cars. Also promising for utility scale, but cycle count is really important for utility scale since they earn money from maximizing cycles as they shift cheap supply to expensive use. They earn nothing when just storing, like all storage systems.
 
Ultimate game changer? No. Not even remotely close.

Even sodium ion batteries, of which I have quite a few sitting on my desk and are currently in production in commercial volume quantities, it's not remotely close to making a big impact, at least not in the near future.

There are plenty of technologies that offer pathways to lower costs, better performance and longer life. The problem is just as Tanj pointed out above, scaling it up!

Look at CATL, LG Chem, BYD, Samsung SDI, SK On and Panasonic. How much money have they invested in production capacity currently for the respective chemistries they produce? Multi-billions of dollars.

When I visited the battery factories late last year discussing sodium ion batteries, the main reason the Chinese were pursuing it was to reduce reliance on imported materials when making lithium battery variants. The local provincial governments were subsiding costs massively to just bring it to parity with LFP and NMC costs. There's potential for sodium ion batteries to become cheaper, but even with a 3GWh factory, the numbers aren't that favorable for sodium ion cells. CATL has all the technology to produce them but they're not pursuing it actively. Why? Again, because of the fact they have nearly 500GWh of production capacity invested in lithium ion batteries. It would cannibalize sales and directly compete with what they're currently producing. Sodium ion batteries also suffer from lower energy density, the specific energy is higher than what Xebec mentioned above, the ones I have are around 140-150Wh/kg, but as far as cost vs lead acid, both sodium and lithium batteries are already better than lead acid batteries, especially if you consider their real capacity when factoring deeper discharge cycles. The biggest challenge with sodium ion is the operating voltage range is very very wide, which makes BMS a bigger challenge, a full charge is 4v, low voltage cut-off is as low as 1.5v, a 4 cell pack would need 16v to fully charge and drain down to 6v. It's not difficult to design circuits to handle the wide operating voltage range, but now wire gauge does become a bigger factor since you'd need wires to handle the greater than 2.5x difference in ampacity between when the battery is fully charged and nearly fully discharged. But that's a bit of a tangent with sodium ion cells, let's get back to silicon anodes.

You could argue that silicone anode would be a simple swap for existing lithium ion factories but it's still a huge undertaking. Lithium battery producers are fairly risk averse because if even the smallest defects leave the assembly line, it could cause a catastrophic recall. Major cell companies already invest a ton of money into new chemistries on the horizon, SK even has an affiliate SM Materials making silicon anodes, Samsung is investing heavily into solid state, all these companies are constantly innovating materials with incremental improvements, but don't expect huge leaps in the battery space. With newcomers, without massive financial backing and without a partnering top lithium cell manufacturer to partner up with, it's impossible to make any impact on the battery market. There's dozens of smaller scale players even in China with multi GWh of production capacity and they simply can't compete with the bigger companies in economics of scale, despite the fact they've invested hundreds of millions to billions of dollars.

Besides, at this point, for most part, even current chemistries are good enough, at least for automotive applications. Saving weight would help and improving energy density would as well, but we're not going to get huge improvements in charging time because the massive amounts of electricity needed to quickly charge will start to be limited by the transmission lines, a 100kWh pack with a 10 minute recharge would require 600kW on the transmission line, you'd need medium voltage lines to the charging station to be able to handle even charging one single car. A 250kW Tesla Supercharger works with three phase 480v, that's still 500+ amps, I don't think it's practical to use 480v for chargers higher than 350kW, or at the very least, it would require a LOT of thick wires to distribute from the transformer dropping down medium voltage line to all the individual chargers at a charging station. 1000 MCM cables are almost 2 inches in diameter and can handle 500-800 amps depending on insulation rating, they're not easy to work with, very heavy and very pricey. That'll be a challenge for battery charging architectures as well, we're seeing 800v, 900v and 1000v battery architectures, the wiring needs and insulation on the car itself will become a bigger factor with weight.
 
Ultimate game changer? No. Not even remotely close.
Fantastic post, Peter!

I think the new chemistries are more likely for uses like aircraft and drones, maybe some military stuff, where superior energy density is willing to pay and the addressable market is small enough for a new entrant to manage. New technologies generally never succeed by directly replacing an incumbent, they almost always start with some market not well addressed.

The obsession with fast chargers is driven by two things:
- folks who think EVs are exactly like ICE, and so are trying to build "gas stations". Apart from a small scattering on long distance routes, this is a mistake.
- inequitable access to lower rate pervasive charging. For example, apartment dwellers or neighborhoods with no electricity available at parking spots. This is also a problem at workplaces, where they waste their money building a few fast chargers that are a nightmare to schedule instead of widely providing a few kW per outlet at ordinary parking spaces.

I don't see the continued obsession with fast charging as really building the future. It solves only a small part of the problem. Wide access to power connections, bidirectional for virtual power stations, and at places where vehicles are parked during parts of the day with the cheapest electricity, those should come ahead of 600kW charging for infrastructure build.
 
The obsession with fast chargers is driven by two things:
- folks who think EVs are exactly like ICE, and so are trying to build "gas stations". Apart from a small scattering on long distance routes, this is a mistake.
- inequitable access to lower rate pervasive charging. For example, apartment dwellers or neighborhoods with no electricity available at parking spots. This is also a problem at workplaces, where they waste their money building a few fast chargers that are a nightmare to schedule instead of widely providing a few kW per outlet at ordinary parking spaces.

I don't see the continued obsession with fast charging as really building the future. It solves only a small part of the problem. Wide access to power connections, bidirectional for virtual power stations, and at places where vehicles are parked during parts of the day with the cheapest electricity, those should come ahead of 600kW charging for infrastructure build.

I agree, but I think unfortunately we're in the chicken and egg scenario there. It's only going to be when the market switches over mainly to EVs that we'll see people really complaining enough to get shared parking spaces (work, apartments, townhomes) largely switched over to these "everywhere but slower" charger configurations. I know several people in apartment and townhome scenarios, and if they want an EV and not use fast chargers, they will need to deal with HOAs or other organizations that tend to make your life difficult/expensive if you challenge anything status quo. Hopefully we're not too far away from this scenario.

Bi-directional is a bit of a different challenge -- they really need to figure out how to warranty (and market) batteries for those scenarios given current cycle and usage limitations. (.. Car owners used to miles and years, but not 'cycles'). I'm sure they'll overcome this but I think that's one reason this has been slow to develop.

On a side note, Tesla built the Cybertruck battery pack to support 400V or 800V via relays rather than transformers. It's basically 2 x 400V packs that can operate in parallel or series, depending on the need. Which I thought was a cool solution for enabling higher power rates without higher losses or expense.

P.S. Peter - great info on the comparative battery chemistries!
 
I think the new chemistries are more likely for uses like aircraft and drones, maybe some military stuff, where superior energy density is willing to pay and the addressable market is small enough for a new entrant to manage. New technologies generally never succeed by directly replacing an incumbent, they almost always start with some market not well addressed.
Yes, exactly that! Primarily it'll be high performance edge case uses that will first be willing to pay the premium for any of the novel chemistries with premium performance, such as cells with silicon anodes and solid state cells. The biggest market for batteries by far is automotive at the moment, but ESS is going to grow rapidly if governments expect to hit renewable energy targets, this is where sodium ion batteries could potentially play a big role if they can bring down the cost enough, and that's what I've been trying to evaluate, but at the moment, every sodium ion cell I've evaluated performed worse than LFP in almost every metric, including price. The one thing they are a little better at is complete discharge, that's where all lithium batteries suffer dramatically but it's not a common occurrence to begin with with proper BMS so I don't see it making a big difference. Cold temperature performance is a little better too, but there are tweaks that can be done to LFP and NCM cells to improve in that regards at a higher price point as well.
The obsession with fast chargers is driven by two things:
- folks who think EVs are exactly like ICE, and so are trying to build "gas stations". Apart from a small scattering on long distance routes, this is a mistake.
- inequitable access to lower rate pervasive charging. For example, apartment dwellers or neighborhoods with no electricity available at parking spots. This is also a problem at workplaces, where they waste their money building a few fast chargers that are a nightmare to schedule instead of widely providing a few kW per outlet at ordinary parking spaces.

I don't see the continued obsession with fast charging as really building the future. It solves only a small part of the problem. Wide access to power connections, bidirectional for virtual power stations, and at places where vehicles are parked during parts of the day with the cheapest electricity, those should come ahead of 600kW charging for infrastructure build.
Agreed. Unfortunately for me, I do a lot of long distance driving, my expectation is to do a quick fill up and get back on the road as quickly as possible. That and I do haul heavy loads occasionally and drive quite a few miles offroad to my house in the middle of nowhere, so unfortunately, I don't see any EVs in my future. But for the vast majority of the people out there who only drive to commute and drive long distance trips once or twice a year, faster charging is completely unnecessary. And you're completely on point regarding few fast chargers vs having more slow chargers, standard level 2 chargers are cheap, a single level 3 charger costs as much as 20-30 level 2 chargers for the charging equipment only, the focus should be on making those ubiquitous. Unfortunately here in the US, we're quite constrained on the rest of deployment costs, i.e. installation and complying with all the safety codes; the way I see them deploying these chargers in China and other Asian countries wouldn't pass code here, but I don't necessarily see their deployments as unsafe by any means. Some of that is also dealing with the substantially higher instances of vandalism here in the US but that's a whole different rabbit hole!

On a side note though, the super high power chargers will be absolutely necessary for the trucking industry if we're to see wide-spread adoption with commercial vehicles. For your average passenger vehicle, as I mentioned above, lithium batteries are already for most part, cheap enough, durable enough and reliable enough for the vast majority of people out there and with the exception of the longer recharge times, their performance is on par if not better than most ICE cars. But for long distance trucking, battery energy density does need to improve 3-5 times to make them competitive, and I only bring it up because, well, the trucking industy's share of air pollution is substantially higher proportionally compared to the number of vehicles they make up on the road. If we're to be serious about reducing carbon emissions for transportation in the US, trucks definitely have to be addressed, whether it's by using batteries, or, this is where H² fuel cells could actually be a better use case!

I agree, but I think unfortunately we're in the chicken and egg scenario there. It's only going to be when the market switches over mainly to EVs that we'll see people really complaining enough to get shared parking spaces (work, apartments, townhomes) largely switched over to these "everywhere but slower" charger configurations. I know several people in apartment and townhome scenarios, and if they want an EV and not use fast chargers, they will need to deal with HOAs or other organizations that tend to make your life difficult/expensive if you challenge anything status quo. Hopefully we're not too far away from this scenario.
Oh boy, the red tape to deal with to get enough chargers for HOAs or apartments/townhomes/condos is just suffocating to say the least! Well, I guess it's not only with chargers, even with solar panels or deploying more efficient water heaters, we just have too many dang regulations to deal with!
Bi-directional is a bit of a different challenge -- they really need to figure out how to warranty (and market) batteries for those scenarios given current cycle and usage limitations. (.. Car owners used to miles and years, but not 'cycles'). I'm sure they'll overcome this but I think that's one reason this has been slow to develop.

On a side note, Tesla built the Cybertruck battery pack to support 400V or 800V via relays rather than transformers. It's basically 2 x 400V packs that can operate in parallel or series, depending on the need. Which I thought was a cool solution for enabling higher power rates without higher losses or expense.
I've tested quite a few different cells, the simple and easy way to address the bi-directional charge cycles wouldn't be all too difficult to implement and it can be handled purely by software. NCM/NCMA chemistries are routinely capable of at least 1000 full charge/discharge cycles, LFP chemistries, I see them hitting 3000-5000 cycles these days. These are full DoD cycles, which is obviously really harsh on the batteries, so if you don't discharge the battery too deep or charge it too high, you can get a lot more life out of them. Typically battery life cycles are calculated from cycling 100% DoD, from their full charge voltage rating (i.e. around 4.2-4.3v for NCM/NCMA/LCO/etc. or 3.6-3.65v for LFP) to their full discharge rating (around 3.0v for NCM/NCMA/LCO/etc. to 2.5v for LFP). If you charge up to only 90% instead of the full 100%, you can easily get another 20-30% cycle life out of the cells, and if you cycle between 80% charge to 20% charge, for most chemistries, you can often triple the cycles (if not more!). So sacrificing 40% of the capacity to get 3 times the charge cycles, you'd still end up with more usable power, say, for a 100kWh pack with 1000 cycles, instead of 100,000kWh cycled, 60kWh x 3000 cycles for 180,000kWh cycled. For technical people, it wouldn't be hard to understand the difference and as long as the bi-directional system can be configured to set discharge and charge points, it wouldn't be too difficult to have an EV provide a good amount of power for home use while not degrading the battery too rapidly. Going from 1000 cycles to 3000 cycles would mean nearly 10 years of service as a backup/renewable power source for your home if the home is configured with solar or wind or some other renewable energy source, in addition to its use as the battery for the car, that seems like a pretty decent deal. But even for bi-directional, the bigger issue I see at the moment is cost with the current implementations offered, for example Ford with their Charge Station Pro and Home Integration System charges over $4000 for their hardware alone, not including installation or any additional costs if a breakout panel is needed. With LFP chemistry, 2000-3000 cycles seems to be the bare minimum these days, I've run across cells already capable of 4000-6000 cycles or more. And LTO is easily 20000+ cycles though the energy density and cost is not attractive by any means! 😲

As for the 400v/800v, GM Ultium based cars had the capability of switching between voltages earlier than Tesla, actually Tesla was rather hesitant to even consider 800v!
 
Electric trucks for port to warehouse should be relatively low hanging fruit
Of course! Though that also depends on where the initial distribution warehouse is these days, even down in SoCal where I spend most of my time, the warehouses they're building are further and further inland because of the sky high costs. And the truckers I've spoken to, if the warehouses they're dropping off at is close to port, they have to make multiple trips a day anyway, they'll still need a quick charge to top off to make another delivery. Knowing California, they're going to legislatively force the trucking industry to meet its goals :cautious:
 
But for the vast majority of the people out there who only drive to commute and drive long distance trips once or twice a year, faster charging is completely unnecessary. And you're completely on point regarding few fast chargers vs having more slow chargers, standard level 2 chargers are cheap, a single level 3 charger costs as much as 20-30 level 2 chargers for the charging equipment only, the focus should be on making those ubiquitous.
I believe understanding that not everybody needs an EV soon is key to smooth transition. A lot of FUD is written saying (ll;dr) "EV is screwed because monster trucks cannot be EV" which is sometimes luddite propaganda. We got to almost 2M EVs sold last year by reaching a product level practical for a lot of people. Next step is more practical, more people. Every vehicle, everyone? Not necessary. And the infrastructure should be the same: invest in what is widely practical and useful for the cases that we are ready to solve. Then iterate.
Oh boy, the red tape to deal with to get enough chargers for HOAs or apartments/townhomes/condos is just suffocating to say the least! Well, I guess it's not only with chargers, even with solar panels or deploying more efficient water heaters, we just have too many dang regulations to deal with!
Yep, but it is reaching the point where prices will fall if there is no EV infra in a building or neighborhood. Watch how fast the regulations change and HOAs move when people realize that. They have already started. It will help if the best-practice examples are "deliver 3kW NEMA 14-30R sockets to every second parking stall, with metered access keyed to cellphones" and just wait for the service companies popping up ready to do the install in return for a cut on the rate. Those companies will upgrade as needed. Just get away from the stupid Level 3 installations at apartments which are so foolish and impractical. Sure, put a few of those in for the occasions someone is in a hurry.

It is about planning a broad sweep, methodical and effective use of money and installers.
for a 100kWh pack with 1000 cycles, instead of 100,000kWh cycled, 60kWh x 3000 cycles for 180,000kWh cycled.
If you reckon 1kWh can be arbitraged for 10 cents by a typical city utility if they took an enlightened attitude (definitely not yet typical), since it replaces peak purchases AND reduces peak stress on the network, then 1kWh cycled 3,000 times will earn $300. That is a miserable return for a commercial venture, probably looking at 10 years for that 3,000 times with a cell maybe costing $200 per kWh, but it is a reasonable benefit to a vehicle with a well managed (AI running in the cloud cooperating with schedule management and auctions set by car owners) V2G functionality. As you say, offset by concerns of subtracting from the vehicle life, so the V2H might reasonably use only 1/3rd of the cycles.

It would help a lot if the battery is designed to swap and recycle in 10 years, at which point the replacement may be better and cheaper.

It will take time for folks to adjust to the new economic patterns of EV ownership.
As for the 400v/800v, GM Ultium based cars had the capability of switching between voltages earlier than Tesla, actually Tesla was rather hesitant to even consider 800v!
The practicality of this has shifted in the last decade due to vast improvements in the electronic conversion. Even Tesla has radically improved their controllers, so they know 800V is feasible now.
 
For short-haul distribution vans, EVs may work well (eg Rivian EDV, GM Brightdrop). But clearly for long-haul trucking, there are a different set of challenges, as mentioned above. What are your opinions on whether hydrogen is a better fit?
 
I see H2 as around 15 years behind EV in ramping up. The fuel cells are deployed in very few vehicles, with cheaper ones having low power/weight and the higher density power being deployed at unknown cost. The next generation Honda may be the first time we see both reasonable power and cost, though there is little information about it yet.

H2 also has large distribution problems. A French company wants to use swappable cylinders, which seems clever and pencils out well for fuel density. Long-haul trucks may be able to work with a small number of fuel stations. For wider use, there will need to be a lot of capital injected to make enough service stations ready.

And then there is the problem of generating green hydrogen, which is far from solved. The cycle efficiency currently wastes well over half the source electricity and the costs of electrolyzers may be slowly ammortized when driven by intermittent wind and solar, which are generally cited as the most likely sources since large amounts of stranded peak energy should be cheap.

20 years from now H2 is likely going to be a big deal. I don't see it helping significantly in the next 10. It is long term strategic which should not divert from more immediate actions.
 
I believe understanding that not everybody needs an EV soon is key to smooth transition. A lot of FUD is written saying (ll;dr) "EV is screwed because monster trucks cannot be EV" which is sometimes luddite propaganda. We got to almost 2M EVs sold last year by reaching a product level practical for a lot of people. Next step is more practical, more people. Every vehicle, everyone? Not necessary. And the infrastructure should be the same: invest in what is widely practical and useful for the cases that we are ready to solve. Then iterate.
Absolutely, we've just become a polarized society, it's hilarious to read the extremes on either side! Still, economics drives the decision, in California or all of Europe where gas costs are off the charts, EVs make economical sense for the masses, and also areas where they put a premium on registration costs for ICE cars. Can't please everyone but even with a few percent improvement in energy density over time, we'll probably get to a point where for personal vehicles, EVs will overwhelmingly make sense for everyone within a generation.

Yep, but it is reaching the point where prices will fall if there is no EV infra in a building or neighborhood. Watch how fast the regulations change and HOAs move when people realize that. They have already started. It will help if the best-practice examples are "deliver 3kW NEMA 14-30R sockets to every second parking stall, with metered access keyed to cellphones" and just wait for the service companies popping up ready to do the install in return for a cut on the rate. Those companies will upgrade as needed. Just get away from the stupid Level 3 installations at apartments which are so foolish and impractical. Sure, put a few of those in for the occasions someone is in a hurry.

It is about planning a broad sweep, methodical and effective use of money and installers.
Good point, as you mentioned, that trend has already started, and it's not just for homes/residences, but for parking structures and parking lots in other industries. But as I was watching a clip earlier today where some ass-hat cut off cords for all the chargers at a Chargepoint charging station, a little disheartening to see the crap we have to deal with in the US. Might not even be from someone who has a grudge against EVs, some transients are stealing them for copper scrap? 🤦‍♂️

If you reckon 1kWh can be arbitraged for 10 cents by a typical city utility if they took an enlightened attitude (definitely not yet typical), since it replaces peak purchases AND reduces peak stress on the network, then 1kWh cycled 3,000 times will earn $300. That is a miserable return for a commercial venture, probably looking at 10 years for that 3,000 times with a cell maybe costing $200 per kWh, but it is a reasonable benefit to a vehicle with a well managed (AI running in the cloud cooperating with schedule management and auctions set by car owners) V2G functionality. As you say, offset by concerns of subtracting from the vehicle life, so the V2H might reasonably use only 1/3rd of the cycles.

It would help a lot if the battery is designed to swap and recycle in 10 years, at which point the replacement may be better and cheaper.

It will take time for folks to adjust to the new economic patterns of EV ownership.
The economics definitely varies tremendously by region. I don't think the payback period for arbitrage makes sense in the vast majority of the US and don't really foresee it making much sense anytime in the near future, but seeing the shocking ToU rates for SCE and PG&E, as high as 66 cents/kWh... might make sense sooner rather than later. That's the big issue we have in the battery industry with residential ESS systems, the economics are impossible to justify. The only way to make sense of it is if power/grid quality goes south...which with all the fires and shut down events from high winds in California, is slightly helping.

As for battery swap, seems too much of an engineering challenge to get automakers to conform to that, but I also see some innovative players moving in on battery recycling tech so at least none of the materials, or less of the materials will be going to waste. Even contemporary lithium battery costs are still going on a downward trajectory, this is why I have so little confidence in any of these new battery chemistries or technologies having much chance. Some of the companies making flow batteries I spoke to years ago, they were targeting being competitive with lithium battery prices at the prices then, they couldn't fathom how much lower lithium battery prices actually ended up. Same conundrum for sodium ion cell makers right now as well, lithium battery prices are a moving target that's chugging along, while also building up massive capacity. Some back of the napkin numbers I ran not too long ago suggests we'll reach enough cumulative 7 year lithium battery production to hold a day's worth of global electricity use sometime in the 2040s. Global solar capacity is expected to hit 5TW by 2030...that's nameplate capacity and would produce more than the daily needs of the entire US, it's going to take a tremendous amount of storage to balance out the duck curve!

For short-haul distribution vans, EVs may work well (eg Rivian EDV, GM Brightdrop). But clearly for long-haul trucking, there are a different set of challenges, as mentioned above. What are your opinions on whether hydrogen is a better fit?
Hydrogen has potential to be a better fit. It's still a ways away to be competitive, but the main reason I find it to be potentially compelling is, unlike batteries, which require huge upfront capital costs in manufacturing them for storing energy, with hydrogen, it's a matter of storing the gas. When we're discussing large scale storage, enough to store energy for a metropolis or larger, the cost of storage becomes a magnitude cheaper for storing hydrogen versus uses batteries. Of course, this is easier said than done and massive infrastructure needs to be built out as well, though that can be done more gradually by targeting specific applications. With the amount of renewable energy sources that's going to be deployed in the near future, if we only rely on batteries, we'll have to curtail electricity production quite a bit as any batteries deployed will quickly be topped off from the grid, large scale hydrogen storage can keep these power generation systems running for as much storage space we have, underground salt caverns can make for reasonably cheap storage even despite potential losses.

We'll need all that hydrogen if we're looking to use alternative fuels for long haul trucks, ships and potentially even aircraft. Volumetric energy density isn't there for aircraft, we'd have to look at other synthetic fuels made using hydrogen, such as methanol or ammonia. That transition is already underway in the ocean freight industry now, more than half of all new vessels in production are dual fuel vessels and can accommodate methanol or ammonia fuels. The costs are high right now, but when done on the scale that's happening in lithium batteries and solar/wind deployment, those challenges can be addressed. All the more if we get some gen IV nuclear power plants running with higher temperature/pressure steam generation and unlike existing nuclear power plants that's primarily used for baseload, they can continue running during high renewable production time just chugging along producing hydrogen/synthetic fuels.

I personally think we should spread out and consider various energy mediums and electricity generation methods to not put all our eggs in one basket. Geographically, it's necessary, it's quite ridiculous for reach blanket renewable energy targets for every country when the natural resources available and the population demands for each country is vastly different. You have vast countries like Norway and Canada with fairly small populations and rich in fossil fuels that can already hit high renewable energy proportions from all the available hydroelectric resources, then there are countries like South Korea, Japan and Taiwan that are polar opposites, very high population density and very little land and next to no fossil fuel reserves. Some 75% of Taiwan's electricity generation is from fossil fuels and they plan on phasing out nuclear power plants that make up 10%, makes me wonder how TSMC or Samsung will hit renewable energy targets without relying on overseas carbon credits! :cautious:
 
Agreed, would be best to let the market place multiple bets, then have them all compete for share. Unfortunately, politicians like picking "winners"...
 
Agreed, would be best to let the market place multiple bets, then have them all compete for share. Unfortunately, politicians like picking "winners"...
True that! But I do understand the need to subsidize new technologies to get some of it off the ground for whatever reason. It's good to see there are developments on all these different alternatives though.

I live completely off the grid and rely entirely on solar/batteries for all our home electricity. We have a large propane tank for home heating, cooking and water heating that I'm trying to wean off of, we switched out cooking entirely to electric induction, home heating to electric heat pump + wood stove (to at least be carbon neutral) and I'm trying to wrap my head around how to heat water...it's so easy to get mini-split heat pumps for water heating in the rest of the world, it's almost impossible to get one here in the US. We installed so much solar to ensure we can get through the winter months, and for most part, we can, but that means during the summer, we only tap in to 25% of the potential daily production, the other 75% is simply curtailed. Even though round-trip efficiencies of hydrogen or synfuel alternatives are very low, the ability to store more than a week or two's worth of fuel would be an absolute game changer for off grid folks!
 
I see H2 as around 15 years behind EV in ramping up. The fuel cells are deployed in very few vehicles, with cheaper ones having low power/weight and the higher density power being deployed at unknown cost. The next generation Honda may be the first time we see both reasonable power and cost, though there is little information about it yet.

H2 also has large distribution problems. A French company wants to use swappable cylinders, which seems clever and pencils out well for fuel density. Long-haul trucks may be able to work with a small number of fuel stations. For wider use, there will need to be a lot of capital injected to make enough service stations ready.

And then there is the problem of generating green hydrogen, which is far from solved. The cycle efficiency currently wastes well over half the source electricity and the costs of electrolyzers may be slowly ammortized when driven by intermittent wind and solar, which are generally cited as the most likely sources since large amounts of stranded peak energy should be cheap.

20 years from now H2 is likely going to be a big deal. I don't see it helping significantly in the next 10. It is long term strategic which should not divert from more immediate actions.

The problem with hydrogen is safety. If the compressed hydrogen tank on car damaged,and hydrogen leak out in a confined space such as underground car park. It can lead to deadly explosion,much more deadly than those lithium battery burning accidents
 
The problem with hydrogen is safety. If the compressed hydrogen tank on car damaged,and hydrogen leak out in a confined space such as underground car park. It can lead to deadly explosion,much more deadly than those lithium battery burning accidents
The problem with any high energy density fuel or storage method is safety. I don't see hydrogen being any more dangerous in that regards and the incident rates, however limited they are, don't suggest it's substantially worse than alternatives. Same arguments were made when CNG and LPG fuels came out and that didn't turn out to be the case either. Each system is going to come with its own unique set of dangers and challenges. Hydrogen with extremely high pressure or cryogenic storage requirements and material embrittlement issues, ammonia and methanol exposure being very toxic, certain lithium battery chemistries having explosive thermal runway events, so on and so forth. Get into an accident with any of these fuels, you're going to have a bad day!

Personally I'd like to see methanol become the fuel of choice; it's a lot easier to handle and store, not nearly as volatile as gasoline and much easier to put out methanol fires, much higher energy density than H², flexible enough to be used for ICE and fuel cells, can be made from various feed stock, etc. The big negative is even lower RT efficiency than H² but here's to hoping renewables will become so cheap and pervasive that these solutions become viable! LCoE of PV solar and wind is already lower than natural gas or any fossil fuel/nuclear power plant and will only get cheaper. And Gen IV nuclear power plants sound pretty interesting too, all fascinating stuff in the pipeline!
 
I see H2 as around 15 years behind EV in ramping up. The fuel cells are deployed in very few vehicles, with cheaper ones having low power/weight and the higher density power being deployed at unknown cost. The next generation Honda may be the first time we see both reasonable power and cost, though there is little information about it yet.

H2 also has large distribution problems. A French company wants to use swappable cylinders, which seems clever and pencils out well for fuel density. Long-haul trucks may be able to work with a small number of fuel stations. For wider use, there will need to be a lot of capital injected to make enough service stations ready.

And then there is the problem of generating green hydrogen, which is far from solved. The cycle efficiency currently wastes well over half the source electricity and the costs of electrolyzers may be slowly ammortized when driven by intermittent wind and solar, which are generally cited as the most likely sources since large amounts of stranded peak energy should be cheap.

20 years from now H2 is likely going to be a big deal. I don't see it helping significantly in the next 10. It is long term strategic which should not divert from more immediate actions.
Hydrogen is 15 years behind in spite of a 15+ year head start. So this will tell you a lot about the S curve in the relative performance of these technologies. By the time hydrogen is viable, the performance/cost of Li batteries will be many times better than today.

There are many paths to improvement in Li batteries. On cathode, there are chemistry improvements, the most promising is adding a little manganese to LFP for LMFP batteries. On anode you will see increased silicon content in anode material. There can also be improvements in binders and additives that will provide incremental performance improvements. One of the most promising areas of improvement is the separator material, where new separators are being designed that inhibit dendrite growth, which allows chemistries to be pushed even further. Changes to cell format can also make a difference in cost, like Tesla 4680 battery, or large format prismatic cells like BYD blade. There are improvements at the pack level, like blade battery pack and other cell to pack technologies. Finally, there is a lot that can be gained from new manufacturing process, like Tesla dry coating process or semi solid battery process.

The Li battery industry is still very young. Li batteries were only invented in the 1980s. Compare this to silicon transistor, which was invented in 1950s. Batteries don't have as fast of an improvement rate as transistors, so we will not see a 1000x performance/cost improvement over the next 30 years, but I would bet a 10x improvement is very possible. In the same time, I doubt hydrogen will even have a 2x improvement.
 
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